Fuel cells are classified
according to their operating temperature, electrolyte and the
corresponding conductive ions. The low-temperature group
consists of Polymer Electrolyte Membrane Fuel Cells (PEMFC), Phosphoric Acid Fuel Cells
(PAFC) and Alkaline Fuel Cells (AFC). Solid
Oxide Fuel Cells (SOFC) and Molten Carbonate Fuel Cells (MCFC) are high-temperature fuel cells. All electrode reactions and electrolyte mechanisms are
summarised in the figure below.
Typical properties of the different fuel cell
types are listed in the table below:
AFC
PEMFC
PAFC
MCFC
SOFC
Operating
temperature
70-220°C
Up
to 120°C
130-220°C
600-800°C
700-1000°C
Electrolyte
Potassium
hydroxide (KOH)
Polymer
membrane
Concentrated
phosphoric acid
Melted
Li/K carbonate
Solid
oxide ceramic
Fuels
Pure
hydrogen
Hydrogen
(+reformate),
methanol
Hydrogen,
natural gas
Hydrogen,
natural gas
Hydrogen,
natural gas
Power
range realised
Up
to 12 kW
Up
to 250 kW
Up
to 1 MW
Up
to 2 MW
Up
to 10 MW
Application
Space,
sub-marine
Portable,
mobile, APU, CHP
Small
power plants, APU, CHP
Power
plants
Power
plants, APU, CHP
APU - Auxiliary Power Unit, CHP - Combined
Heat and Power